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We present the fabrication of a novel Starfruit‐shaped metal‐organic framework (SMOF) composed of zirconium and Tetra(4‐carboxyphenyl)porphine linkers. The SMOF exhibits a unique morphology with edge‐sharing two‐dimensional (2D) nanosheet petals. Our investigation unravels a captivating transformation process, wherein three‐dimensional (3D) shuttle‐shaped MOFs form initially and subsequently evolve...
The use of trifluoromethyl containing compounds is well established within medicinal chemistry, with a range of approved drugs containing C−CF3 and O−CF3 moieties. However, the utilisation of the N−CF3 functional group remains relatively unexplored. This may be attributed to the challenging synthesis of this unit, with many current methods employing harsh conditions or less accessible reagents. A...
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