The contradiction between the world's growing energy demand and the current energy crisis is sharpening. In this context, conversion of CO2 by photo‐ and electrocatalytic reduction, has been the most promising strategy to turn CO2 into valuable fuels (e.g., CO, CH4, C2H5OH, etc.). However, traditional catalysts, such as metals, transitional‐metal oxides or sulfides, have an unsatisfactory production selectivity and efficiency. In their Minireview article on page 14026 ff., H. Lin, J. Zhu et al. report the current progress of MOFs in photo‐/electrocatalytic reduction of CO2 by modifying their metal centers, organic linkers, and pores. Future directions of study are also highlighted to satisfy the requirement of practical applications.