An efficient synthesis of 2‐di‐tert‐butylphosphanylmethylpyrrole (HpyrmPtBu2), by treating 2‐dimethylaminomethylpyrrole (HpyrmNMe2) with tBu2PH at 135 °C in the absence of any solvent, has allowed the preparation of the new PGeP germylene Ge(pyrmPtBu2)2 (1), by treating [GeCl2(dioxane)] with LipyrmPtBu2, in which the Ge atom is stabilized by intramolecular interactions with one (solid state) or both (solution) of its phosphane groups. Reactions of germylene 1 with Group 10 metal dichlorido complexes containing easily displaceable ligands have led to [MCl{κ3P,Ge,P‐GeCl(pyrmPtBu2)2}] [M=Ni (2), Pd (3), Pt (4)], which have an unflawed square‐planar metal environment. Treatment of germylene 1 with [AuCl(tht)] (tht=tetrahydrothiophene) rendered [Au{κ3P,Ge,P‐GeCl(pyrmPtBu2)2}] (5), which is a rare case of a T‐shaped gold(I) complex. The hydrolysis of 5 gave the linear gold(I) derivative [Au(κP‐HpyrmPtBu2)2]Cl (6). Complexes 2–5 contain a PGeP pincer chloridogermyl ligand that arises from the insertion of the Ge atom of germylene 1 into a M−Cl bond of the corresponding metal reagent. The bonding in these molecules has been studied by DFT/NBO/QTAIM calculations. These results demonstrate that the great flexibility of germylene 1 makes it a better precursor to PGeP pincer complexes than the previously known germylenes of this type.