The preparation and structural characterization of a series of chromium phthalocyanine complexes with multiple metal and ring oxidation states were achieved using PcCrII (1) (Pc=phthalocyanine) or PcCrII(THF)2 (1⋅THF2) as starting materials. The reaction of soluble 1⋅THF2 with Br2 or I2 gave the PcCrIII halide complexes PcCrX(THF) (X=I/I3, Br; 3, 4, respectively). Treatment of 1 with 0.5 equivalent of PhIO or air generated the dinuclear [PcCr(THF)]2(μ‐O) (5), whereas the addition of one equivalent of AgSbF6 to 1 resulted in oxidation to THF‐solvated octahedral [PcCrIII(THF)2]SbF6 (6). The reduction of 1 with three sequential equivalents of KEt3BH resulted in the isolation of [K(DME)4][Pc3−CrII] (7), [K(DME)4]2[Pc4−CrII] (8) and [K6(DME)4][Pc4−CrI]2 (9), respectively. The reduced products are deep purple in colour, with visible absorption maxima between 500–580 nm. The ring‐reduced complexes 7 and 8 are monomeric, whereas 9 is a 1D chain of dinuclear [PcCr]2 units with intercalated K+ cations and supported by Cr−Cr interactions of 2.988(2) Å. Addition of four equivalents of KC8 resulted in the demetallated product PcK2(DME)4 (10), which has a 1D chain structure. The isolation and structural characterization of new PcCr complexes spanning five oxidation states, including rare examples of crystalline reduced Pc‐ring species emphasizes the broad redox activity and stability of phthalocyanine‐based complexes.