Several bis‐triazolium‐based receptors have been synthesized and their anion‐recognition capabilities have been studied. The central chiral 1,1′‐bi‐2‐naphthol (BINOL) core features either two aryl or ferrocenyl end‐capped side arms with central halogen‐ or hydrogen‐bonding triazolium receptors. NMR spectroscopic data indicate the simultaneous occurrence of several charge‐assisted aliphatic and heteroaromatic C−H noncovalent interactions and combinations of C−H hydrogen and halogen bonding. The receptors are able to selectively interact with HP2O73−, H2PO4−, and SO42− anions, and the value of the association constant follows the sequence: HP2O73−>SO42−>H2PO4−. The ferrocenyl end‐capped 72+⋅2 BF4− receptor allows recognition and differentiation of H2PO4− and HP2O73− anions by using different channels: H2PO4− is selectively detected through absorption and emission methods and HP2O73− by using electrochemical techniques. Significant structural results are the observation of an anion⋅⋅⋅anion interaction in the solid state (2:2 complex, 62+⋅[H2P2O7]2−), and a short C−I⋅⋅⋅O contact is observed in the structure of the complex [82+][SO4]0.5[BF4].