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Thin skin: Pt‐alloy catalysts, such as annealed Pt3Ni(111) (see STM image; color changes mark a single atomic step), with a surface layer of pure platinum, termed a Pt‐skin surface, have very different electrochemical adsorption properties to monometallic Pt. The adsorption of hydrogen is largely suppressed (see CV, (—) Pt3Ni(111)‐skin versus (••••) Pt(111)), making it hard to determine the electrochemically...
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