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Rare examples of PSn bonded cations (see structure; purple Al, gray C, green Cl, orange P, red Sn) are formed in reactions of Me3P or Me2PCH2CH2PMe2 with Me3SnCl or nBu2SnCl2 in the presence of a halide abstracting agent. The demonstrated versatility of the reactions, structures and bonding arrangements bodes well for the development of a diverse PSn chemistry by exploiting coordination chemistry...
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