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Catching the anchor: Although diboranes(4) commonly react by way of BB bond activation, reaction of B2Mes2Br2 with [Pt(PEt3)3] led to the selective oxidative addition of one BBr bond; the resulting diboran(4)yl complex shows an unexpected dative PtB bonding interaction to the second boron center of the diboran(4)yl ligand. Oxidative addition of one BBr bond in B2(NMe2)2Br2 to [Pt(PiPr3)2] enabled...
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