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Arylate then cyclize: A palladium(II)‐catalyzed cascade sequence has been developed to provide highly diastereomerically enriched cis‐1‐aryl‐3‐vinyl isoindolines (see scheme). The method uses commercially available aryl boronic acids and boroxine compounds containing a variety of electron‐rich, ‐neutral, or ‐poor aromatic groups. Ts=4‐toluenesulfonyl.
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