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Although N‐heterocyclic carbenes have been well‐studied, the simplest aminocarbene, aminomethylene H−C̈−NH2, has not been spectroscopically identified to date. Herein we report the gas‐phase preparation of aminomethylene by high‐vacuum flash pyrolysis of cyclopropylamine and subsequent trapping of the pyrolysate in an inert argon matrix at 12 K. Aminomethylene was characterized by matching matrix...
Carbene In ihrer Zuschrift auf S. 5346 charakterisieren P. R. Schreiner und A. K. Eckhardt das einfachste Aminocarben, Aminomethylen, in festem Ar mittels IR‐ und UV/Vis‐Spektroskopie.
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