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In an effort to characterize the electronic states of ethylenedione, OCCO, photoelectron‐photofragment coincidence (PPC) spectroscopy was applied to measure anions at m/z 56 and 57 using a pulsed discharge of glyoxal vapor and N2O. PPC measurements at a photon energy of 3.20 eV yield photoelectron spectra in coincidence with either neutral photofragments or stable neutral products. The measurements...
Mit neuen Informationen über die neutralen Produkte nach der Elektronenablösung mittels Photoelektron‐Photofragment‐Koinzidenz‐Spektroskopie sowie theoretischen Studien können die von Sanov et al. als erste Charakterisierung der langlebigen Triplet‐Radikale OCCO und HOCCO veröffentlichten Spektren kritisch hinterfragt werden. In ihrer Zuschrift auf S. 5492 zeigen R. E. Continetti et al., dass die...
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