The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
Ein T‐förmiges Nickel(I)‐Metalloradikal …… mit starrem Acridan‐basierten PNP‐Ligand zeigt eine beispiellose offenschalige Reaktivität. In ihrer Zuschrift auf S. 9630 ff. zeigen Y. Lee und C. Yoo, dass das frei zugängliche halbgefüllte
‐Orbital der radikalischen d9‐Spezies die Fähigkeit zur homolytischen Spaltung von σ‐Bindungen (z. B. H−H, N−N, C−C) über einen Zwei‐Elektronen‐Prozess unter Beteiligung...
A T‐shaped NiI complex was synthesized using a rigid acridane‐based pincer ligand to prepare a metalloradical center. Structural data displays a nickel ion is embedded in the plane of a PNP ligand. Having a sterically exposed half‐filled
orbital, this three‐coordinate NiI species reveals unique open‐shell reactivity including the homolytic cleavage of various σ‐bonds, such as H−H, N−N, and...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.