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Lipopolysaccharides from Bacteroides vulgatus represent interesting targets for the treatment of inflammatory bowel diseases. However, efficient access to long, branched and complex lipopolysaccharides remains challenging. Herein, we report the modular synthesis of a tridecasaccharide from Bacteroides vulgates through an orthogonal one‐pot glycosylation strategy based on glycosyl ortho‐(1‐phenylvinyl)benzoates,...
Lipopolysaccharides from Bacteroides vulgatus represent interesting targets for the treatment of inflammatory bowel diseases. In their Research Article (e202301351), Guozhi Xiao and co‐workers accomplished the first synthesis of a tridecasaccharide motif from Bacteroides vulgatus lipopolysaccharides by a strategy involving orthogonal one‐pot glycosylation reactions based on glycosyl ortho‐(1‐phenylvinyl)benzoates,...
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