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Cobaltabisdicarbollide (COSAN) anions have an unexpectedly rich self‐assembly behavior, which can lead to vesicles and micelles without having a classical surfactant molecular architecture. This was rationalized by the introduction of new terminology and novel driving forces. A key aspect in the interpretation of COSAN behavior is the assumption that the most stable form of these ions is the transoid...
Ein trigonal‐bipyramidaler und ein kubischer heterobimetallischer Käfig wurden mit Eisen(II)‐ und Palladium(II)‐Bausteinen gemäß dem Molecular‐Library‐Ansatz aus demselben einkernigen Metalloliganden aufgebaut. Das Ligandensystem wurde so entworfen, dass der Aufbau durch Subkomponenten‐Selbstorganisation möglich war. Dieser Ansatz ermöglicht es, sterische Spannung um die Eisen(II)‐Zentren in das System...
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