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Eine neue Gold‐katalysierte decarbonylierende Inden‐Synthese wird beschrieben. Synergistische σ,π‐Aktivierung von Diin‐Substraten führt zu Goldvinyliden‐Intermediaten, die nach der Addition von Wasser in Goldacyl‐Spezies übergehen – ein Typ von Organogold‐Verbindung, über den bisher nur sehr selten berichtet wurde. Für diese Spezies beweisen wir eine Extrusion von CO, einen in der homogenen Gold‐Katalyse...
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