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Die durch das Übergangsmetallnitrid‐Ion [NbN]+ vermittelte, katalytische Reduktion von N2O durch CO wurde unter thermischen Bedingungen in der Gasphase mittels FT‐ICR‐Massenspektrometrie und quantenchemischen Rechnungen untersucht. Während das [NbN]+/[ONbN]+‐System die Oxidation von CO durch N2O katalysiert, ermöglichen die Systeme [Nb]+/[NbO]+ und [NbO]+/[Nb(O)2]+ zwar die Oxidation von [Nb]+ und...
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