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Metall‐organische Gerüste Mithilfe von reduzierendem Dampf lassen sich CuII‐Knotenpunkte im Metall‐organischen Gerüst (MOF) HKUST‐1 in CuI überführen. L. B. Sun et al. zeigen in der Zuschrift auf S. 10210, dass sich so hierarchische Poren im ursprünglich mikroporösen MOF bilden.
Hierarchically porous metal–organic frameworks (HP‐MOFs) have attracted great attention owing to their advantages over microporous MOFs in some applications. Despite many attempts, the development of a facile approach to generate HP‐MOFs remains a challenge. Herein we develop a new strategy, namely the modulation of cation valence, to create hierarchical porosity in MOFs. Some of the CuII metal nodes...
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