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Wir zeigen die Synthese einer DNA‐kodierten Makrocyclenbibliothek (DKMB) über sieben Schritte auf DNA. Diese Bibliothek wurde, inspiriert von Polyketid‐ und gemischten Peptid‐Polyketid‐Naturstoffen, mit stark variierender Grundstruktur geplant. Die hohe Vielfalt wurde mit selbst synthetisierten Bausteinen erreicht, deren Herstellung allerdings arbeitsintensiv ist. Diese Studie zeigt die Wichtigkeit...
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