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For the first time, multinuclear noble‐metal clusters have been successfully stabilized by Ti‐oxo clusters. Two unprecedented Ag6@Ti16‐oxo nanoclusters with precise atomic structures were prepared and characterized. The octahedral Ag6 core has strong Ag−Ag bonds (ca. 2.7 Å), and is further stabilized by direct Ag−O−Ti coordination interactions. Moreover, as a result of different acidic/redox conditions...
Mehrkernige Silberspezies können im Inneren von Titan‐Oxo‐Clustern stabilisiert werden. L. Zhang, J. Zhang et al. berichten in ihrer Zuschrift auf S. 11422 über zwei derartige Kern‐Schale‐Ag6@Ti16‐Oxo‐Nanocluster, deren Strukturen an die traditionelle chinesische Silberwährung “yuanbao” erinnern. Die oktaedrischen Ag6‐Cluster innerhalb der Halbleiter‐Ti‐O‐Schale zeigen verschiedene Orientierungen,...
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