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Eine Silica‐Nanostruktur mit rundem Boden (SiJAR) und einem Mn‐Silikat‐Deckel wurde in der Zuschrift auf S. 16473 von Amit Kumar, In Su Lee et al. durch thermische Festkörperkonversionschemie hergestellt. SiJAR wurde als katalytischer Nanoreaktor eingesetzt, der Nanokristalle und Enzyme beherbergt, die asymmetrische Aldolreaktionen in lebenden Zellen durchführen.
Nanodevices, harvesting the power of synthetic catalysts and enzymes to perform enantioselective synthesis inside cell, have never been reported. Here, we synthesized round bottom jar‐like silica nanostructures (SiJARs) with a chemo‐responsive metal‐silicate lid. This was isolated as an intermediate structure during highly controlled solid‐state nanocrystal‐conversion at the arc‐section of silica...
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