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Eine neue formale [3+2]‐Cycloaddition von Cyclopropylacetalen und Aldehyden wurde entwickelt, in welcher die resultierenden drei Stereozentren der dreifach substituierten Tetrahydrofurane in hoch diastereoselektiver Weise gebildet werden. Die hier beschriebene Methode ist stereokomplementär zu den meisten bereits bekannten Cycloadditionen von Malonat‐Diestern, beruht auf der kurzzeitigen Generierung...
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