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Das Verständnis der Eigenschaften von Radikalen, die ausgehend von Si‐haltigen, schweren Analoga von Alkenen gebildet werden, ist wichtig für ihre Anwendung in der radikalischen Polymerisation. Sterische und elektronische Substituenteneffekte in Phosphasilenen stabilisieren nicht nur die Si=P‐Doppelbindung, sondern beeinflussen auch die Struktur und Natur der gebildeten Radikale. Wir berichten hier...
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