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Tiara[5]arene , fünffach symmetrische Makrocyclen aus Phenoleinheiten, die über para‐substituierte Methylenbrücken verknüpft sind, wurden von H. Zuilhof, A. C.‐H. Sue et al. synthetisiert. In ihrem Forschungsartikel auf S. 4023 werden Aufbau und Derivatisierung gezeigt, ebenso wie Festkörperstrukturen, Wirt‐Gast‐Eigenschaften in Lösung sowie die Anwendung als nichtporöse adaptive Kristalle für die...
Tiara[5]arenes (T[5]s), a new class of five‐fold symmetric oligophenolic macrocycles that are not accessible from the addition of formaldehyde to phenol, were synthesized for the first time. These pillar[5]arene‐derived structures display both unique conformational freedom, differing from that of pillararenes, with a rich blend of solid‐state conformations and excellent host–guest interactions in...
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