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Die Oxygenierung von Methan mittels Sauerstoff erfolgt in einem Zweiphasensystem aus Perfluorhexan und Wasser unter Umgebungsbedingungen. In ihrer Zuschrift auf S. 2148 zeigen K. Ohkubo und K. Hirose, dass das Chlordioxidradikal (ClO2.) ein effektives Oxidationsmittel ist für die aerobe Oxygenierung von Methan zu Methanol und Ameisensäure unter Lichteinstrahlung. Die Methanol‐ und Ameisensäure‐Ausbeuten...
The chlorine dioxide radical (ClO2.) was found to act as an efficient oxidizing agent in the aerobic oxygenation of methane to methanol and formic acid under photoirradiation. Photochemical oxygenation of methane occurred in a two‐phase system comprising perfluorohexane and water under ambient conditions (298 K, 1 atm). The yields of methanol and formic acid were 14 and 85 %, respectively, with a...
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