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Understanding what controls the strength of bonding of adsorbed intermediates to transition‐metal surfaces is of central importance in many technologies, especially catalysis and electrocatalysis. Our recently measured bond enthalpies of −OH, −OCH3, −O(O)CH and −CH3 to Pt(111) and Ni(111) surfaces are fit well (standard deviation of 7.2 kJ mol−1) by a predictive equation involving only known parameters...
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