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Flavine und Flavoproteine wurden als Photokatalysatoren für die Aktivierung Metall‐basierter Prodrugs eingesetzt. In der Zuschrift auf S. 3197 zeigen F. López‐Gallego, L. Salassa et al., wie diese Photokatalysatoren in Gegenwart von Elektronendonoren und blauem Licht PtIV‐ und RuII‐Komplexe in potenziell toxische PtII‐ und RuII‐OH2‐Verbindungen überführen. Die Flavoproteine miniSOG und NADH‐Oxidase...
Recent advances in bioorthogonal catalysis promise to deliver new chemical tools for performing chemoselective transformations in complex biological environments. Herein, we report how FAD (flavin adenine dinucleotide), FMN (flavin mononucleotide), and four flavoproteins act as unconventional photocatalysts capable of converting PtIV and RuII complexes into potentially toxic PtII or RuII−OH2 species...
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