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Carboranes. B9‐functionalized carboranylphosphines with bulky electron‐donating substituents display an extremely electron‐releasing character, as reported by Evamarie Hey‐Hawkins et al. in their Research Article (e202218648). The compounds exert a high steric demand, which allows the mesityl derivatives to form stabilized phosphoniumyl radical cations.
Die Synthese der ersten B9‐verbundenen Carboranylphosphane (B9‐Phos) mit zwei Carboranyleinheiten sowie der Zugang zu B9‐Phos‐Liganden mit sperrigen elektronen‐schiebenden Substituenten, die bisher als unerreichbar galten, werden vorgestellt. Die elektrochemischen Eigenschaften der B9‐Phos‐Liganden wurden untersucht und die Fähigkeit der Mesityl‐Derivate, stabilisierte Phosphoniumylradikalkationen...
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