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s‐Block‐Metallcarbenoide sind Carbensynthons und werden in einer Vielzahl organischer Reaktionen eingesetzt. Hierbei besitzen Carbenoide eine enge Struktur‐Reaktivitäts‐Beziehung, die jedoch aufgrund der hohen Reaktivität und Empfindlichkeit dieser Reagenzien bisher nur wenig verstanden ist. Hier berichten wir von systematischen VT‐ und DOSY‐NMR‐Studien, Strukturanalysen sowie DFT‐Rechnungen anhand...
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