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Pd‐catalyzed sequences involving oxidative addition, cyclization, and termination through intermolecular nucleophile capture have tremendous utility. Indeed, they can generate a plethora of different polycyclic structures possessing a diverse range of functionality. However, one area of deficiency for Pd0/PdII variants is the ability to conclude them with oxygen‐based species. Inspired by the recent...
A palladium‐catalyzed highly selective 3,4‐bifunctionalization of 3‐I‐o‐carborane has been developed, leading to the preparation of 3‐alkenyl‐4‐R‐o‐carboranes (R=alkyl, alkynyl, aryl, allyl, CN, and amido) in high to excellent yields. This protocol combines the sequential activation of cage B(3)−I and B(4)−H bonds by Pd migration from exo‐alkenyl sp2 C to cage B(4), which is driven by thermodynamic...
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