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A series of end‐functionalized poly(9,9′‐di‐n‐octylfluorene vinylene)s (EF‐PFVs) with different end groups were obtained by 1) synthesizing EF‐PFV with vinyl end groups by acyclic diene metathesis (ADMET) polymerization with a molybdenum catalyst and termination with an aldehyde and 2) subsequent olefin metathesis of the vinyl group with the molybdenum catalyst followed by Wittig‐type coupling with...
Die Synthese von Polyarylenvinylenen mit verschiedenen Endgruppen wird von K. Nomura et al. in der Zuschrift auf S. 5372 ff. beschrieben. Die endfunktionalisierten Poly(9,9′‐dialkylfluorenvinylen)‐Derivate (EF‐PFVs) wurden durch 1) die Synthese von EF‐PFVs mit Vinyl‐Enden durch Molybdän‐katalysierte acyclische Dienmetathese und Terminierung mit einem Aldehyd und 2) anschließende Olefin‐Metathese mit...
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