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Recent years have witnessed a resurgence of novel, efficient and practical protocols for radical‐mediated cross‐coupling reactions involving N‐(acyloxy)phthalimides (NHPI esters) as redox‐active esters. After the initial discovery of the redox‐active properties of NHPI esters, exciting examples of SET‐based cross‐coupling reactions under thermal or photolytic conditions leading to diverse C–X (X=C,...
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