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An efficient and mild protocol for the direct conversion of arene C−H bonds to C−NH2 without the need for extra deprotection step has been established, and to the best of our knowledge, this is the first time that the synthesis of primary anilines via nickel‐mediated C(sp2)‐H activations has been reported. This approach utilizes 8‐aminoquinoline as the directing group and sodium azide, a cheap and...
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