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An efficient and regioselective three‐component heteroarylation‐nitration of alkenes with imidazo[1,2‐a]pyridines and tert‐butyl nitrite has been developed. The process tolerants a variety of functional groups under mild conditions in the absence of catalysts and additives to give nitro functionalized imidazo[1,2‐a]pyridine derivatives in moderate to good yields. The reaction is also applicable for...
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