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Saturated carbo‐ and heterocyclic building blocks can be readily obtained by the hydrogenation of aromatic carbo‐ and heterocycles. Although a variety of methods have been established to accomplish this transformation for simple arenes, the hydrogenation of aromatic N‐heterocycles is less explored. We herein report a diastereoselective arene hydrogenation which was applied to an array of benzo‐fused...
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