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Covalent organic frameworks (COFs) are crystalline porous polymers formed by a bottom‐up approach from molecular building units having a predesigned geometry that are connected through covalent bonds. They offer positional control over their building blocks in two and three dimensions. This control enables the synthesis of rigid porous structures with a high regularity and the ability to fine‐tune...
In article number 1705553, Thomas Bein and co‐workers provide a comprehensive overview of the covalent organic framework structures realized to date. Advanced synthesis strategies are discussed, as well as applications, which include gas storage, sensing, electrochemical energy storage, and optoelectronics.
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