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In article number 1707536, Jia‐Qi Huang and co‐workers review homogeneous/heterogeneous mediators in Li‐S chemistry and provide a mediator perspective on building high‐energy‐density Li‐S batteries. The twin flowers represent the synergy of heterogeneous and homogeneous mediating strategies. Heterogeneous mediators take care of transformation kinetics and shuttle flooding, while homogeneous mediators...
Lithium–sulfur (Li–S) batteries deliver a high theoretical energy density of 2600 Wh kg−1, and hold great promise to serve as a next‐generation high‐energy‐density battery system. Great progress has been achieved in cathode design to deal with the intrinsic problems of sulfur cathodes, including low conductivity, the dissolution of polysulfide intermediate, and volume fluctuation. However, aiming...
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