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Largely soluble tris(pentafluorophenyl)borane (BCF) has recently emerged as a promising molecular dopant for preparing highly conductive organic thermoelectrics (TEs) using a one‐step solution‐mixing method. However, the unique doping mechanisms that include both undesirable Lewis acid doping with BCF and effective Brønsted acid doping with BCF–water complexes limit its widespread applications. Herein,...
Donor‐Acceptor Polymers
In article number 2207413, Jaeyoung Jang and co‐workers demonstrate the feasibility of regulating the doping mechanisms of donor‐acceptor polymers with tris(pentafluorophenyl)borane (BCF) by utilizing the competitive Lewis acid‐base interactions of BCF with H2O or Lewis basic groups in the polymers. This strategy dramatically improves thermoelectric performances of the doped...
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