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In 2017, a new family of in‐plane, chemically‐ordered quaternary MAX phases, coined i‐MAX, has been reported since 2017. The first i‐MAX phase, (Mo2/3Sc1/3)2AlC, garnered significant research attention due to the presence of chemically ordered Sc within the Mo‐dominated M layer, and the facilitated removal of both Al and Sc upon etching, resulting in 2D i‐MXene, Mo1.33C, with ordered divacancies....
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