In this paper, considering the strategy of integrated Pest Management (IPM), a class of two-prey two-predator system with the Ivlev-type functional response and impulsive effect at different fixed time is established. By using impulsive comparison theorem, Floquent theory and small amplitude perturbation skill, the sufficient conditions for the system to be extinct of prey and permanence are proved. Moreover, we give two sufficient conditions for the extinction of one of two prey and remaining three species are permanent. Numerical simulation shows that there exist complex dynamics for system, such as symmetry-breaking pitchfork bifurcation, periodic doubling bifurcation, chaos, periodic halving cascade. Lastly, a brief discussion is given.