Robust inference based on the minimization of statistical divergences has proved to be a useful alternative to the classical techniques based on maximum likelihood and related methods. Recently Ghosh et al. (2013b) proposed a general class of divergence measures, namely the S-Divergence Family and discussed its usefulness in robust parametric estimation through some numerical illustrations. In this present paper, we develop the asymptotic properties of the proposed minimum S-Divergence estimators under discrete models.