The paper describes the development of nuclear-physical methods of analysis and their applications in Kazakhstan for geological tasks and technology. The basic methods of this complex include instrumental neutron-activation analysis, x-ray fluorescent analysis and instrumental γ-spectrometry. The following aspects are discussed: applications of developed and adopted analytical techniques for assessment and calculations of rare-earth metal reserves at various deposits in Kazakhstan, for technology development of mining and extraction from uranium-phosphorous ore and wastes, for radioactive coal gasification technology, for studies of rare metal contents in chromite, bauxites, black shales and their processing products.