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The β decay of 94Pd and of the 71s isomer of 94Rh was investigated by using total γ-ray absorption techniques. Several levels in 94Rh are established, including a new low-lying isomer characterized by a half-life of 0.48(3)μs and a de-exciting transition of 55keV. E2 multipolarity is determined for this transition by measuring the intensities of its γ-rays and the characteristic X-rays from its electron conversion. On the basis of the measured reduced β-decay transition rates to known 94Ru levels and shell model considerations, the spin-parity of the 71s and the 0.48μs isomers of 94Rh is assigned to be (4+) and (2+), respectively. The β-decay strength distributions measured for 94Pd and the 71s isomer of 94Rh yield Q EC values of 6700(320) and 9750(320)keV for these decays and give evidence for the population of those states below and above the magic N = 50 gap that belong to both components of the 0g spin-orbit doublet.