Based on S wave records of deep teleseisms on Digital Seismic Network of Shanxi Province, shear wave velocity structures beneath 6 stations were obtained by means of S wave waveform fitting. The result shows that the crust is thick in the studied region, reaching 40 km in thickness under 4 stations. The crust all alternatives high velocity layer with low velocity one. There appear varied velocity structures for different stations, and the stations around the same tectonic region exhibit similar structure characteristics. Combined with dominant depth distribution of many small-moderate earthquakes, the correlation between seismogenic layers and crustal structures of high and low velocity layers has been discussed.