A novel polarization splitter based on d-shaped dual-core photonic crystal fiber with gold film is proposed and analyzed by the finite element method. The designed polarization splitter involves side-polishing of photonic crystal fiber and depositing of gold film. The numerical results reveal that the separate length is 0.782 mm and the extinction ratios are -151 and -55 dB for the x- and y-polarized modes at the communication wavelength of 1,550 nm. The bandwidths of the polarization splitter are 40 and 65 nm for the x- and y-polarized modes with extinction ratios better than -20 dB and insertion losses lower than 0.3 dB. This d-shaped dual-core photonic crystal fiber is competitive for polarization splitter.