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Literature information on phase equilibria and materials thermodynamics of the quaternary Si-B-C-N system and its binary (Si-B, Si-C, Si-N, B-C, B-N, C-N) and ternary (Si-B-C, Si-B-N, Si-C-N, B-C-N) subsystems are reviewed. Experimental phase diagrams and thermodynamic data are compared with results from thermodynamic calculations according to the CALPHAD method (CALculation of PHAse Diagrams). Calculated...
The challenge to develop tailor-made precursor molecules for silicon carbide has significantly intensified the progress in synthesis of organosilicon polymers. A critical overview is presented regarding useful synthesis routes towards such molecules with appropriate chemical composition as well as controllable architecture (metal condensation of halogenosilanes or silahalogenocarbons, disproportionation...
Inorganic random networks composed of silicon, boron, nitrogen, and carbon constitute a novel class of ceramics with outstanding durability at elevated temperatures. The only approach known to their synthesis is the pyrolysis of appropriate pre-ceramic polymers, which on their part are either accessible via co-condensation of different molecular species, or by polycondensation of single source precursors...
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