Intelligent design of chemical-process equipment requires accurate thermophysical property values for pure components and mixtures including solutions. Databases used by practicing engineers should include the best numbers available and estimated uncertainties of these numbers. Many important property values have not been measured and must be estimated. Care should be exercised in selecting the estimation method. Property values that are a function of temperature, pressure, and/or composition can be correlated using appropriate equations. Such equations and the number of adjustable parameters in these equations should be selected with care. Examples of determining uncertainties, estimation techniques used, and correlating equations are given.