Surface photovoltage (SPV) spectroscopy has been used for the first time to explore Landau levels of a two-dimensional electron gas (2DEG) in modulation doped InP/InGaAs/InP QW in the quantum Hall regime. The technique gives spectroscopically distinct signals from the bulk Landau levels and the edge states. Evolution of the bulk Landau levels and the edge electronic states is investigated at 2.0 K for magnetic field up to 8 T using SPV spectroscopy.