The soil under intensive cultivation and low addition of crop residues is exposed to erosion and reduction of organic matter. Increases in soil organic matter, cation exchange capacity (CEC) and nutrient availability may occur in no-till systems with legumes and with large additions of organic residues. Nevertheless, some legumes may increase soil acidification through the carbon and nitrogen cycles. An experiment was carried out over 10 years, with 10 cropping systems on a Dark Red Podzolic soil (Paleudult) to evaluate the effect of no-till cropping systems on soil chemical characteristics. Legume cropping systems resulted in the greatest soil organic C gain and the highest ECEC to a depth of 17.5 cm. The increase was greatest at 0 - 2.5 cm layer. Clover systems resulted in the highest soil acidification at 2.5 - 7.5 and 7.5 - 17.5 cm depths. The rate of soil pH decrease at 2.5 - 7.5 cm depth under clover+ t Spergula/maize system was 0.1 unit year-1. Differences in soil acidification affected soil ECEC. Soil exchangeable cation data indicate that nitrate leaching increased soil acidification. Maize yields were greatest in legume systems due to increased N supply.