Spin coating silica films were prepared from acid-catalyzed tetraethoxysilane (TEOS) solutions, and the magnitude of radiative striations formed on the surface of the resulting films was quantitatively evaluated by measuring surface roughness using a contact probe profilometer. Wave-like transverse profiles were obtained on the films prepared. Surface roughness parameters, Ra (arithmetical mean deviation), Rz (ten point height of irregularities) and S (mean spacing of local peaks), were determined. When the gel films were heated at higher temperatures (≤500°C), the film thickness decreased up to 22%, while none of Ra, Rz or S varied with heat-treatment temperature, indicating that the surface of the films is already densified at room temperature. Higher substrate rotation speeds caused decrease in Ra, Rz and S, revealing that the striations decreased both in amplitude and wavelength. Application of viscous sols aged for longer periods of time resulted in increased amplitude (Rz) of striations without change in wavelength (S).