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The morphological structure of monolayers of straight-chain alcohols with 14 to 18 C-atoms are studied. Compression/decompression isotherms are illustrated by images taken with a Brewster angle microscope. Tetradecanol with a plateau region in the surface pressure-area isotherm exhibits circular domains during the phase transition. Decompression leads to the formation of a stable two-dimensional foam...
The surface pressure-area isotherms for a polymer resin spread on an aqueous subphase were invertigated. A time-dependent hysteresis effect was observed on re-expansion of the film. An explanation for this effect is proposed based on the concept of two “welded” monolayers.
The main features of the morphological structure changes during monolayer compression of 1-O-hexadecyl-rac-glycerol are studied by Brewster angle microscopy (BAM). Images of the monolayer related to the corresponding points of the π-A-isotherms are presented and discussed. The results are compared with those obtained for 1-monopalmitoyl-rac-glycerol having only small distinctions in the chemical structure.
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